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Lithium amide : ウィキペディア英語版
Lithium amide

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Lithium amide is an inorganic compound with the chemical formula Li+NH2, i.e. it is composed of a lithium cation, and the conjugate base of ammonia. It is a white solid with a tetragonal crystal structure.
==Lithium amides==
The anionic conjugate bases of amines are known as amides. Thus lithium amide may also refer to lithium salts of amines e.g. Li+NR2. An example of a lithium amide is lithium diisopropylamide (LDA), which is quite commonly used.
Lithium amide can be made by adding lithium metal to liquid ammonia:
:2Li + 2NH3 → 2LiNH2 + H2
Lithium amides in general can be similarly formed, substituting ammonia with the appropriate amine:
:2Li + 2R2NH → 2LiNR2 + H2
Lithium amides are very reactive compounds and can act as strong bases. Unless the nitrogen atom is hindered, as in the case of LDA, they can also act as nucleophiles.

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